Selected Fluid Catalysis Publications

Cobalt(I) Salt Formation in Hydroformylation Catalysis, J. W. Rathke, R. J. Klingler, M. J. Chen, R. E. Gerald II, and K. W. Kramarz, The Chemist 80(1), 9-12 (2003)

Aluminum Oxide Nanotubes, Batteries and Beyond, R. E. Gerald II, D. N. Sears, K. J. Ruscic, R. J. Klingler, and J. W. Rathke, Abstract for Poster Session, Argonne National Laboratory Young Scientist Day Poster Session, Argonne National Laboratory, July 23, 2003

NMR Studies of Confined Molecules in Porous Al₂O₃ Films, R. E. Gerald II, D. N. Sears, K. J. Ruscic, R. J. Klingler, and J. W. Rathke, Abstract, to be presented at 45th Rocky Mountain Conference on Analytical Chemistry, Denver, CO, July 27-31, 2003

Gas Phase Micelles as Minireactors for Catalysis, R. J. Klingler, J. W. Rathke, M. J. Chen, and R. E. Gerald II, Poster, presented at the Basic Energy Sciences Program Review, Argonne National Laboratory, Argonne, IL, May 12-14, 2003

Investigations of Electrochemical Systrems Using Novel Detectors: Toroid Cavity NMR Imagers, R. E. Gerald II, R. J. Klingler, and J. W. Rathke, Poster, presented at the Basic Energy Sciences Program Review, Argonne National Laboratory, Argonne, IL, May 12-14, 2003

Metallophthalocyanine Catalysts for Hydrocarbon Activation, M. J. Chen, J. W. Rathke, R. J. Klingler, and R. E. Gerald II, Poster, presented at the Basic Energy Sciences Program Review, Argonne National Laboratory, Argonne, IL, May 12-14, 2003

Supercritical Phosphine-Modified Hydroformylation Catalysis, J. W. Rathke, R. J. Klingler, M. J. Chen, and R. E. Gerald II, Viewgraphs, presented at the Basic Energy Sciences Program Review, Argonne National Laboratory, Argonne, IL May 12-14, 2003

Toroid Cavity Detectors for Homogeneous Catalysis Studies in Supercritical Fluids, R. E. Gerald II, M. J. Chen, R. J. Klingler, and J. W. Rathke, Presented at the 44th Experimental Nuclear Magnetic Resonance Conf., Savannah, GA, March 30-April 4, 2003

NMR Technology for In Situ Analyses of Coin Cells, R. E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the 5th IBA-HBC Yeager Memorial Symp., Waikoloa Beach, HI, January 7-10, 2003

Flat Metal Conductor Principal Detector Element for NMR Analysis of a Sample, R. E. Gerald II, R. J. Klingler, and J. W. Rathke, U. S. Patent No. 6,469,507 B1, issued October 22, 2002

NMR Technology for In Situ Analyses of Coin Cells, R. E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, U. S. Patent 6,469,507 B1, issued October 22, 2002

Video Toroid Cavity Imager, R.E. Gerald II, J. Sanchez, and J. W. Rathke, Invention Report No. ANL-IN-02-056, July 8, 2002

Passively Shimmed Principal Detector Elements for Toroid Cavity NMR Probes, R.E. Gerald II and J. W. Rathke, Provisional Patent Application, Serial No. 60/363,447, filed March 12, 2002, patent pending

Coin Cell NMR Detector, R.E. Gerald II, R. J. Klingler, and J. W. Rathke, In Chemical Technology Division Annual Technical Report 2001, ANL-02/14, pp. 65-66 (2002)

Gas Phase Micelles as Nanoreactors for Catalysis, R. J. Klingler, R. E. Gerald II, M. J. Chen, and J. W. Rathke, In Chemical Technology Division Annual Technical Report 2001, ANL-02/14, pp. 63-64 (2002)

Advances in ENMR of Solid-State Electrolytes, R.E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Abstracts, 44th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 28-August 3, 2002, Poster No. 232, p. 106 (2002)

In Situ NMR of Electrochemical Systems, R.E. Gerald II, R. J. Klingler, and J. W. Rathke, Abstracts, 8th Int. Symp. on Polymer Electrolytes, Santa Fe, NM, May 19-24, 2002, Oral Presentation, p. 46 (2002)

Electrochemical/NMR Detectors, R.E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Abstracts, 8th Int. Symp. on Polymer Electrolytes, Sante Fe, NM, May 19-24, 2002, Poster Presentation, p. 92 (2002)

Thin Film NMR, R.E. Gerald II, J. W. Rathke, L. E. Iton, and G. S. Schade, Abstracts, Int. Workshop on Nanocomposites: Materials, Neutrons, and Data Interpretation, Argonne National Laboratory, Argonne, IL, March 28-30, 2002, p. 35 (2002)

Synopsis of Poster #9: Thin Film NMR, R.E. Gerald II, J. W. Rathke, L. E. Iton, and G. S. Schade, Abstracts, Int. Workshop on Nanocomposites: Materials, Neutrons, and Data Interpretation, March 28-30, 2002, Argonne National Laboratory, Argonne, IL, March 28-30, 2002, Oral Presentation, p. 35 (2002)

High-Pressure NMR in Homogeneous Catalysis, R. J. Klingler, M. J. Chen, R. E. Gerald II, and J. W. Rathke, Presented at the Workshop on Selectivity in Catalysis, Argonne National Laboratory, Argonne, IL, December 3, 2002

NMR Detection of a Contiguous Alkanethiol Monolayer, R.E. Gerald II, L. E. Iton, and J. W. Rathke, Presented at the Nanohybrid Structures Workshop, University of Chicago, Chicago, IL, November 15-16, 2002

Supercritical Phosphine-Modified Hydroformylation, J. W. Rathke, R. J. Klingler, M. J. Chen, and R. E. Gerald II, Presented at the DOE/BES 2002 Catalysis Contractors’ Meeting and Workshop, Rosemont, IL, September 20-22, 2002

Toroid Cavity NMR Imagers, R.E. Gerald II, J. W. Rathke, R. J. Klingler, K. Woelk, M. J. Chen, E. S. Growney, R. J. Greenblatt, J. Sanchez, and C. R. Jones, Presented at the DOW Chemical Company Scientific Staff Members’ Meeting, Argonne National Laboratory, Argonne, IL, August 21, 2002

Advances in ENMR of Solid-State Electrolytes, R.E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the 44th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, poster session, July 28-August 3, 2002

Cobalt Catalysts for the Hydroformylation of Olefins in Supercritical Carbon Dioxide, M. J. Chen, R. J. Klingler, J. W. Rathke, and R. E. Gerald II, Presented at the CMT Seminar Series, Argonne National Laboratory, Argonne IL, July 10, 2002

In Situ NMR of Electrochemical Systems, R.E. Gerald II, R. J. Klingler, and J. W. Rathke, Presented at the 8th Int. Symp. on Polymer Electrolytes, Santa Fe, NM (Invited) May 19-24, 2002

Electrochemical/NMR Detectors, R.E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the 8th Int. Symp. on Polymer Electrolytes, Sante Fe, NM, May 19-24, 2002

Surface Enhanced NMR, R.E. Gerald II, J. W. Rathke, and G. S. Schade, Presented at the Illinois State University Faculty Members’ Group Discussion, Departments of Chemistry and Physics, Normal, IL, May 8, 2002

Self-Assembled Monolayers Probed by a Novel NMR Detector, R.E. Gerald II, J. W. Rathke, and G. S. Schade, Presented at the University of Illinois at Springfield Group Discussion with Professor K. Dungey, Department of Chemistry, Springfield, IL, May 9, 2002

Characterizing Toroid Cavity Detectors for Investigations of Thin Films, R.E. Gerald II, S. Heckmann, and J. W. Rathke, Presented at the 43rd Experimental Nuclear Magnetic Resonance Conf., Pacific Grove, CA, April 14-19, 2002

Overview of Current Patent Applications, Research Funding, and Experimental Results for Toroid Cavity Detectors, R.E. Gerald II, S. Heckmann, R. J. Klingler, and J. W. Rathke, Presented at a Physical Organometallic Chemistry Group Seminar Series, Argonne National Laboratory, Argonne, IL, April 25, 2002

Catalytic Carbonylations in Supercritical Fluids, M. J. Chen, R. J. Klingler, and J. W. Rathke, Presented at the 223^rd National Meeting of the Am. Chem. Soc., Orlando, FL, April 7-11, 2002

Thin Film NMR, R.E. Gerald II, J. W. Rathke, L. E. Iton, and G. S. Schade, Presented at the Int. Workshop on Nanocomposites: Materials, Neutrons, and Data Interpretation, Argonne National Laboratory, Argonne, IL, March 28-30, 2002

Synopsis of Poster #9: Thin Film NMR, R.E. Gerald II, J. W. Rathke, L. E. Iton, and G. S. Schade, Presented at the Int. Workshop on Nanocomposites: Materials, Neutrons, and Data Interpretation, March 28-30, 2002, Argonne National Laboratory, Argonne, IL (Invited) March 28-30, 2002

In Situ NMR of Thin Films, R.E. Gerald II, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the Analytical Chemistry Seminar Series, Department of Chemistry, University of North Carolina, Chapel Hill, NC (Invited) February 7-10, 2002

Formaldehyde Determination in Supercritical CO2, J. W. Rathke, L. M. Wojcinski, R. J. Klingler, M. J. Chen, and R. E. Gerald II, The Chemist, 78(4), 7-10 (2001)

Microemulsions of Water in Supercritical Carbon Dioxide: An In-Situ NMR Investigation of Micelle Formation and Structure, D. E. Fremgen, R. E. Gerald, E. S. Smotkin, R. J. Klinger, and J. W. Rathke, J. Supercrit. Fluids 19, 287-298 (2001)

Rh(III) Complexes of Singly and Doubly Reduced Phthalocyanine Ligands Generated by Chemical and Electrochemical Reduction., M. J. Chen, R. J. Klingler, and J. W. Rathke, J. Porphyrins Phthalocyanines 5, 442-448 (2001).

Dimeric Aggregates of Five-Coordinated Methyl(phthalocyaninato)Rh(III): 1H NMR Evidence for Staggered and Slipped Cofacial Dimers., M. J. Chen and J. W. Rathke, J. Porphyrins Phthalocyanines 5, 528-536 (2001).

Interfaces, Phenomena, and Nanostructures in Lithium Batteries, A. R. Landgrebe and R. J. Klingler, Eds., Vol. 2000-36, Electrochemical Society, Inc., Pennington, NJ, (2001).

In Situ Nuclear Magnetic Resonance Investigations of Lithium Ions in Carbon Electrode Materials Using a Novel Detector, R.E. Gerald, J. Sanchez, C. S. Johnson, R. J. Klingler, and J. W. Rathke, J. Phys.: Condens. Matter 13, 8269-8285 (2001).

Novel Detector for NMR of Self Assembled Monolayers, R.E. Gerald, J. W. Rathke, and L. E. Iton, Presented at the 42nd Experimental Nuclear Magnetic Resonance Conf., Orlando, FL, March 11-16, 2001

Toroid Cavity NMR Imaging Detector—High Resolution, In-Situ Chemical Analysis of High-Pressure, High-Temperature Industrial Catalysis Processes, R. J. Klingler, J. W. Rathke, M. J. Chen, D. Fremgen, and R. E. Gerald, Presented at the Gordon Research Conference on Chemistry of Hydrocarbon Resources, Ventgura, CA, January 12, 2001

In Situ NMR of Incipient Thin Films of Synthetic Metals, R.E. Gerald, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the NMR Symp. of the 43rd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 29-August 2, 2001

Macroscopic SAMs of Mercury Thiolates Investigated by NMR Spectroscopy and Imaging, R.E. Gerald, J. W. Rathke, and L. E. Iton, Presented at the Fundamentals and Applications of Mesoscopic Self-Assembly Workshop, Materials Research Science and Engineering Center, The University of Chicago, Chicago, IL, April 20, 2001

NMR Paradigms for the Electronic Environments and Mobilities of Lithium in Graphitic Nanoscale Structures, R.E. Gerald, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at Argonne National Laboratory, Argonne, IL, May 2, 2001

Self-Assembled Monolayers as Models for Two-Dimensional Liquid Crystals, R.E. Gerald and J. W. Rathke, Presented at the University of Illinois, Department of Chemistry, School of Chemical Sciences, Urbana-Champaign, IL, May 3, 2001

Phosphine-Modified Hydroformylation in Green Solvent, R. J. Klingler, J. W. Rathke, M. J. Chen, and R. E. Gerald, Presented at the 2001 Spring Symp. of the Catalysis Club of Chicago, BP Naperville Research and Technology Center, Naperville, IL, May 22, 2001

Near-Frictionless Carbon Films as Anodes for Lithium-Ion Batteries, R.E. Gerald, J. Sanchez, R. J. Klinger, J. W. Rathke, A. Erdemir, G. R. Fenske, J. B. Woodford, L. A. Curtis, P. Zapol, and L. E. Iton, Presented at Argonne National Laboratory, Argonne, IL, June 6, 2001

Supercritical Phosphine-Modified Hydroformylation Catalysis, J. W. Rathke, R. J. Klingler, M. J. Chen, and R. E. Gerald, Presented at the Chemrawn XIV World Congress on Green Chemistry: Towards Environmentally Benign Products and Processes, Boulder, CO, June 9-13, 2001

Indirect Nuclear Spin-Spin Couplings in Supercritical CO2 Solutions of Mercuric bis(n-alkanethiolates), R.E. Gerald, M. J. Chen, and J. W. Rathke, Presented at the NMR Symp. of the 43rd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 29-August 2, 2001

Technical Aspects of the Compression Coil Cell Battery Imager, R.E. Gerald, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at the NMR Symp. of the 43rd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 29-August 2, 2001

Analysis of Lithium Intercalants in Graphitic Synthetic Metals, R.E. Gerald, J. Sanchez, R. J. Klingler, and J. W. Rathke, Presented at Argonne National Laboratory, Argonne, IL, February 23, 2001

Applications for Large-Scale Toroid Cavity Detectors, C. R. Jones, Z. Dabi, R. E. Gerald, L. Nunez, R. J. Klingler, and J. W. Rathke, Presented at the NMR Symp. of the 43rd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 29-August 2, 2001

NMR of SAMs on Electrode Surfaces, R.E. Gerald, J. W. Rathke, and L. E. Iton, Presented at the NMR Symp. of the 43rd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 29-August 2, 2001

Phosphine-Modified Cobalt Catalysts for Hydroformylation in Supercritical CO2, M. J. Chen, R. J. Klingler, and J. W. Rathke, Presented at the 10th Int. Symp. and Exhibition on Supercritical Fluid Chromatography, Extraction, and Processing, Myrtle Beach, SC, August 19-22, 2001

High-Pressure NMR Studies in Supercritical Media, R. J. Klingler, J. W. Rathke, M. J. Chen, and R. E. Gerald, Presented at the Sixth Int. Conf. On Carbon Dioxide Utilization, Beaver Run Resort, Breckenridge, CO, September 9-14, 2001

Toroid Cavity NMR Detector Applications at Low and High Magnetic Fields, R.E. Gerald, R. J. Klingler, and J. W. Rathke, Presented at the 42nd Experimental Nuclear Magnetic Resonance Conf., March 11-16, 2001

Homogeneous Catalysis In Supercritical Fluids, J. W. Rathke, R. J. Klingler, M. J. Chen, R.E. Gerald, and D. S. Hacker, Presented at the CMT Technical Seminar, Argonne National Laboratory September 12, 2001

Molecular Orbital and Li-7 NMR Investigation of the Influence of Curved Lattices in Lithium Intercalated Carbon Anodes, G. Sandi, R. E. Gerald, L. G. Scanlon, C. S. Johnson, R. J. Klingler, and J. W. Rathke, J. New Mater. Electrochem. Syst. 3, 13-19 (2000)

Finite-Difference Approach for the High-Precision Analysis of Rotating-Frame Diffusion Images

K. Woelk, B. L. J. Zwank, P. Trautner, E. Lehnhof, J. Bargon, R. J. Klingler, R. E. Gerald II, and J. W. Rathke, J. Magn. Reson. 145, 276-290 (2000)

⁷Li NMR Study of Intercalated Lithium in Curved Carbon Lattices, R.E. Gerald II, R. J. Klingler, G. Sandi, C. Johnson, L. Scanlon, and J. W. Rathke, J. Power Sources 89, 237-243 (2000)

Near-Electrode Imager, J. W. Rathke, R. J. Klingler, K. Woelk, and R. E. Gerald, U.S. Patent No. 6,046,592, issued April 4, 2000

Supercritical Carbonylation Catalysis, J. W. Rathke, R. J. Klingler, M. J. Chen, and L. M. Wojcinski, Presented at the American Chemical Society Meeting, San Francisco, CA, March 26-31, 2000

Toroid Cavity NMR Detector for Operation at 600 MHz, M. A. ter Horst, R. E. Gerald, R. J. Klingler, and J. W. Rathke, Presented at the 41st Experimental Nuclear Magnetic Resonance Conference, Pacific Grove, CA, April 9-14, 2000

Application of the Near Electrode Imager to Lithium Polymer Electrolyte Battery Systems, R.E. Gerald, R. J. Klingler, and J. W. Rathke, Presented at the Structure, Dynamics and Charge Transport in Polymeric Materials Theory Workshop, Argonne National Laboratory, Argonne, IL, June 19-23, 2000

Disclosure of the Rotational Exchange Gradient Imager, R.E. Gerald, R. J. Klingler, and J. W. Rathke Presented at the 42nd Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 2, 2000

Fundamental NMR Investigations of Conduction Ions in Anode and Electrolyte Materials Using the Near Electrode Imager, R.E. Gerald II, R. J. Klingler, and J. W. Rathke, Presented at the 50th American Crystallographic Association Conf., St. Paul, MN, June 22-27, 2000

Large Sample MAS NMR Spectroscopy of Gas Hydrates, J. S. Schuetz, C. R. Jones, R. E. Gerald II, R. J. Klingler, J. W. Rathke, V. Thieu, and Y. Halpern, Presented at the SMASH NMR Symposium, Argonne, IL, June 16-19, 2000

8-fluoro-8-methyl-calix[4]pyrrole: An NMR Study of Neutral Anion Receptor, C. R. Jones, R. E. Gerald II, M. J. Chen, R. J. Klingler, J. W. Rathke, M. Marquez, and Kraft, R&D, Presented at the SMASH NMR Symposium, Argonne, IL, July 16-19, 2000

High-Pressure NMR Studies of Supercritical Carbonylation Catalysis, J. W. Rathke, R. J. Klingler, M/ J. Chen, and L. M. Wojcinski, Presented at the 2000 National Laboratory Catalysis Conference, Argonne, IL, October 12-13, 2000

High-Pressure NMR Characterization of Micellar Systems for Catalysis, R. Klingler, David Fremgen, Rex Gerald II, and Jerome Rathke, Presented at the 2000 National Laboratory Catalysis Conference, Argonne, IL, October 12-13, 2000

NMR Imaging of Fuel Cell and Battery Components, R. Klingler, Rex Gerald II, and Jerome Rathke, Presented at the University of Chicago Review of the Chemical Technology Division, Argonne IL, September 13, 2000

Hydrogen Atom Transfer Processes in Catalysis, R. Klingler and Jerome Rathke, Presented at the Basic Energy Sciences Program Review, Argonne, IL, October 26-29, 1999.

Catalytic Carbonylations in Supercritical Carbon Dioxide, J. Rathke and R. Klingler, Presented at the Basic Energy Sciences Program Review, Argonne, IL, October 26-29, 1999.

Metallophalocyanine Catalysts in Hydrocarbon Activation, M. Chen and J. Rathke, Presented at the Basic Energy Sciences Program Review, Argonne, IL, October 26-29, 1999.

Carbonylation with Cobalt Catalysts, J. W. Rathke, K. W. Kramarz, R. J. Klingler, M. J. Chen, D. E. Fremgen, and R. E. Gerald II, Trends in Organometallic Chemistry 3, 201-209 (1999)

⁷Li NMR Imaging at the Surface of an Aerospace Alloy, R.E. Gerald, L. Nuñez, R. J. Klingler, and J. W. Rathke, The Chemist 76(2), 45-50 (1999)

Toroid NMR Probes for the In Situ Examination of Homogeneous Cobalt Hydroformylation Catalysts at High Pressures and Temperatures, K. W. Kramarz, R. J. Klingler, D. E. Fremgen, and J. W. Rathke, Catal. Today 49(4), 339-352 (1999)

NMR Spectroscopy, J. W. Rathke, R. J. Klingler, R. E. Gerald, D. E. Fremgen, K. Woelk, S. Gaemers, and C. J. Elsevier, in Chemical Synthesis Using Supercritical Fluids, Eds., P. G. Jessop and W. Leitner, Wiley-VCH, Weinheim, pp. 165-194 (1999)

Studies of Electrolyte Penetration in Carbon Anodes by NMR Techniques, G. Sandí, R. E. Gerald, R. J. Klingler, J. W. Rathke, K. A. Carrado, and R. E. Winans, Proc. of the Lithium Battery Symp., 194th Electrochem. Soc. Meeting, Boston, MA, November 1-6, 1998, Vol. 98-16, pp. 11-18 (1999)

Evaluation and Design of Toroid Cavity Probes Based on Calculated Distortions, E. S. Growney, G. Friedman, R. E. Gerald, R. J. Klingler, J. W. Rathke, and L. Nuñez, Program Binder for the 40th Experimental Nuclear Magnetic Resonance Conf., Orlando, FL, February 28-March 5, 1999, p. 129 (1999)

Recent Developments in Toroid Cavity NMR Spectroscopy, Rheology, and Imaging, K. Woelk, R. E. Gerald, R. J. Klingler, and J. W. Rathke, Presented at the 41st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

NMR Detection and Imaging of Gas Phase Micelles, D. E. Fremgen, R. E. Gerald, R. J. Klingler, E. S. Smotkin, and J. W. Rathke, Presented at the 41st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

Imaging Diffusion of Small Molecules in a Toroid Cavity NMR Probe, R.E. Gerald, E. T. Chainani, E. S. Growney, D. E. Fremgen, L. Nuñez, R. J. Klingler, and J. W. Rathke, Presented at the Small Molecule NMR Conf., Argonne, IL, August 15, 1999

Magnetic Resonance Imaging of Polymer Electrolytes and Insertion Electrodes, R. J. Klingler, R. E. Gerald, and J. W. Rathke, Presented at the Advanced Lithium Solid State Batteries Workshop, Towson, MD, July 13-15, 1999

Hydroformylation in Gas Phase Microemulsions, D. E. Fremgen, R. J. Klingler, r. E. Gerald, M. J. Chen, J. W. Rathke, and E. S. Smotkin,, Presented at the Spring Symp. of the Catalysis Club of Chicago, Chicago, IL, May 12, 1999

Passive-Shimming Designs of Toroid Cavity Probes Using Spectral Distortion Parameters, E. S. Growney, R. E. Gerald, R. J. Klingler, J. W. Rathke, and G. Friedman, Submitted to the 41st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

NMR Spectroscopy and Imaging of an Electrochemical Cell with a Carbon Working Electrode, R.E. Gerald, G. Sandí, R. J. Klingler, and J. W. Rathke, Presented at the 41^st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

Distribution of Crystalline and Amorphous Polymer Electrolyte in an Electrochemical Cell, R.E. Gerald, E. T. Chainani, R. J. Klingler, and J. W. Rathke, Presented at the 41^st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

Applications of Toroid Cavity NMR Detectors to Metals, Polymers, Radioactive Materials and Supercritical Fluids, R.E. Gerald, D. E. Fremgen, L. Nuñez, D. T. Reed, R. J. Klingler, J. W. Rathke, and K. Woelk, Presented at the 41^st Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 30-August 5, 1999

In Situ Studies in Carbon Anodes by NMR Techniques, G. Sandí, R. E. Gerald, R. J. Klingler, J. W. Rathke, K. A. Carrado, and R. E. Winans, Presented at the Eveready Battery Company, Westlake, OH, February 15, 1999

Toroid Cavity NMR Detector: Application to Battery Research, R.E. Gerald, R. J. Klingler, J. W. Rathke, and G. Sandí, Presented at the Eveready Battery Company, Westlake, OH, February 15, 1999

Gas Phase Micelles as Microreactors for Oxo Catalysis, D. E. Fremgen, E. S. Smotkin, R. J. Klingler, and J. W. Rathke, Presented at the DOE National Laboratory Research Symp., Albuquerque, NM, February 24-25, 1999

Toroid NMR Studies of Some Catalytic Carbonylations, Jerome W. Rathke, R. J. Klingler, Michael J. Chen, and David E. Fremgen, Presented at the General Electric Corporate R&D CPTL Seminar Series, Schenectady, NY, August 5, 1999

Recent Advances in Metallaphthalocyanine-Catalyzed Carbon-Hydrogen Bond Activation, M. J. Chen and J. W. Rathke, Trends in Inorganic Chemistry 5, 29-41 (1998)

Hydrogen Activation in Oxo Catalysis, R. J. Klingler and J. W. Rathke, The Chemist 75(3), 23-28 (1998)

Paramagnetic Rh(III) Complexes from Reactions of Phosphines with Hydride-Bridged and Non-Bridged Rhodium Phthalocyanine Dimers: Metal-to-Ligand Charge Transfer Induced by Phosphines, M. J. Chen, L. M. Utschig, and J. W. Rathke, Inorganic Chemistry 37(22), 5786-5792 (1998)

In Situ Imaging of Charge Carriers in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, G. Sandí, and K. Woelk, In Chapter of Spatially Resolved Magnetic Resonance, Eds., P. Blümler, B. Blümich, R. Botto, and E. Fukushima, Wiley-VCH, New York (1998)

Imaging Diffusion with Non-Uniform B₁ Gradients, K. Woelk, B. L. J. Zwank, J. Bargon, R. J. Klingler, R. E. Gerald, and J. W. Rathke, In Chapter 8 of Spatially Resolved Magnetic Resonance, Eds., P. Blümler, B. Blümich, R. Botto, and E. Fukushima, Wiley-VCH, New York (1998)

Oxygen Atom Transfer from µ-Oxo-bis[1,4,8,11,15,18,22,25-octakis(trifluoromethyl)phthalocya ninato]dirhodium(III): Evidence for an Fe(IV) = O Intermediate, M. J. Chen, D. E. Fremgen, and J. W. Rathke, J. Porphyrins Phthalocyanines 2, 473-482 (1998)

A Novel Fermentation Pathway in a Mutant Escherichia coli Producing Succinic Acid, Acetic Acid, and Ethanol, M. I. Donnelly, C. S. Millard, D. R. Clark, M. J. Chen, and J. W. Rathke, Appl. Biochem. Biotechnol. 70-72, 187-198 (1998)

In Situ NMR Analysis of Charge Carriers in Polymer Electrolytes, R.E. Gerald, R. J. Klingler, J. W. Rathke, G. Sandí, and K. Woelk, Program and Abstracts, 40th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 25–August 1, 1998, p. 46 (1998)

Toroid Cavity NMR Detector: Application to Electrochemical Systems, R.E. Gerald, R. J. Klingler, J. W. Rathke, G. Sandí, and K. Woelk, Program and Abstracts, 40th Rocky Mountain Conf. on Anaytical Chemistry, Denver, CO, July 25–August 1, 1998, p. 119 (1998)

Flow and Rheological Studies Using Toroid-Cavity NMR, K. Woelk, R. E. Gerald, P. Trautner, B. L. J. Zwank, J. Bargon, R. J. Klingler, and J. W. Rathke, Program and Abstracts, 40th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 25–August 1, 1998, pp. 157-158 (1998)

Applications of NMR for Nondestructive Evaluation of Nuclear Materials, E. S. Growney, R. E. Gerald, R. J. Klingler, J. W. Rathke, L. Nuñez, and S. E. Aumeier, Program and Abstracts, 40th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 25–August 1, 1998, p. 130 (1998)

Supercritical Hydroformylation Catalysis, J. W. Rathke, R. J. Klingler, and M. J. Chen, Proc. of the Fourth DOE/BES Research Conf. on Homogeneous Catalysis and Organometallic Chemistry, Baltimore, MD, June 3-7, 1998, pp. 17-19 (1998)

Rh(III) Complexes of Singly and Doubly-Reduced Phthalocyanine Ligands Generated by Chemical and Electrochemical Reduction, M. J. Chen and J. W. Rathke, Presented at the Second Int. Symp. on Phthalocyanines, Edinburgh, Scotland, September 21-23, 1998

Boundary Element Technique for Calculations of Field and Spectral Distortions, E. S. Growney, G. Friedman, R. E. Gerald, R. J. Klingler, and J. W. Rathke, Presented at the Workshop on Computational Electromagnetics in Magnetic Resonance, College Station, TX, May 30–June 1, 1998

Gas Phase Micelles as Microreactors for Catalysis, D. E. Fremgen, R. J. Klingler, and J. W. Rathke, Presented at the Spring Symp. of the Catalysis Club of Chicago, Chicago, IL, May 8, 1998

Nuclear Magnetic Resonance (NMR) Spectroscopy in High-Pressure/High-Temperature Catalysis, K. W. Kramarz, R. J. Klingler, and J. W. Rathke, Presented at the 215th Am. Chem. Soc. National Meeting, Dallas, TX, March 29–April 2, 1998

High Pressure In-Situ NMR Spectroscopy of Phosphine Modified Cobalt Carbonyl Oxo Catalysts, K. W. Kramarz, R. J. Klingler, and J. W. Rathke, Presented at the Shell Oil Company, Houston, TX, January 19, 1998

Toroids in NMR Spectroscopy, J. W. Rathke, R. J. Klingler, R. E. Gerald, K. W. Kramarz, and K. Woelk, Prog. Nucl. Magn. Reson. Spectrosc. 30, 209-253 (1997)

Method of Solubilizing Phthalocyanines and Metallophthalocyanines, J. W. Rathke, M. J. Chen, and C. M. Fendrick, Statutory Invention Registration No. H1695, issued November 4, 1997

In Situ Measurements of Ion Mobility in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, and K. Woelk, Program Binder for the 38th Experimental Nuclear Magnetic Resonance Conf., Orlando, FL, March 23-27, 1997, p. 10 (1997)

In Situ Imaging of Charge Carriers in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, G. Sandí, and K. Woelk, Abstracts, Fourth Int. Conf. on Magnetic Resonance Microscopy, Albuquerque, NM, September 21-25, 1997, p. 48 (1997)

Imaging Diffusion in Gels, Polymers, and Solids, K. Woelk, B. L. J. Zwank, J. Bargon, R. J. Klingler, R. E. Gerald, and J. W. Rathke, Abstracts, Fourth Int. Conf. on Magnetic Resonance Microscopy, Albuquerque, NM, September 21-25, 1997, p. 61 (1997)

Ion Transport Properties Determined by In-Situ NMR Imaging, R. J. Klingler, R. E. Gerald, and J. W. Rathke, Abstracts, Advanced Non-Aqueous Battery Technology Research and Development Workshop, Hunt Valley, MD, October 15-17, 1997, pp. 82-84 (1997)

High-Pressure NMR Studies of Oxo-Type Catalysts, R. J. Klingler, K. W. Kramarz, and J. W. Rathke, Book of Abstracts, Part 1, 214th Am. Chem. Soc. National Meeting, Las Vegas, NV, September 7-11, 1997, Abstract No. 168 (1997)

High Pressure In Situ NMR Spectroscopy of Cobalt Oxo Catalysts, K. W. Kramarz, R. J. Klingler, and J. W. Rathke, Abstracts, 15th North American Catalysis Soc. Meeting, Chicago, IL, May 18-23, 1997, p. 149 (1997)

Ring Opening Metathesis Polymerizations in Supercritical Fluids, D. E. Fremgen, M. J. Chen, and J. W. Rathke, Abstracts, Catalysis Club of Chicago, Spring Symp., Evanston, IL, April 2, 1997 (1997)

Iron Phthalocyanine-Catalyzed Oxygen Atom Transfer Reactions, M. J. Chen and J. W. Rathke, Abstracts, Catalysis Club of Chicago, Spring Symp., Evanston, IL, April 2, 1997

High-Pressure NMR Studies of Oxo-Type Catalysts, R. J. Klingler, K. W. Kramarz, and J. W. Rathke, Presented at the Am. Chem. Soc. Meeting, Las Vegas, NV, September 7-11, 1997

In Situ Measurements of Ion Mobility in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, and K. Woelk, Presented at the 30th Great Lakes Regional Am. Chem. Soc. Meeting, Chicago, IL, May 28-30, 1997

A Novel Fermentation Pathway in a Mutant Escherichia coli Producing Succinic Acid, Acetic Acid, and Ethanol, M. I. Donnelly, C. S. Millard, D. R. Clark, M. J. Chen, and J. W. Rathke, Presented at the 19th Symp. on Biotechnology for Fuels and Chemicals, Colorado Springs, CO, May 4-8, 1997

In Situ Diffusion Measurements in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, and K. Woelk, Program Binder for the 38th Experimental Nuclear Magnetic Resonance Conf., Orlando, FL, March 23-27, 1997

Hydrido(1,4,8,11,15,18,22,25-octa-n-pentylphthalocyanin ato)rhodium Dimers: Single-Crystal X-ray Structure and the Isomerization of the Four Isomers, M. J. Chen, L. Nuñez, J. W. Rathke, and R. D. Rogers, Organometallics 15(9), 2338-2344 (1996)

Nuclear Resonance Tomography with a Toroid Cavity Detector, K. Woelk, J. W. Rathke, and R. J. Klingler, Patent No. 5,574,370, issued November 12, 1996

In Situ NMR Spectroscopy Studies of Hydroformylation Catalysts Using High Pressure Toroid Probes, K. W. Kramarz, R. J. Klingler, and J. W. Rathke, Abstracts, Sixth Int. Conf. on the Chemistry of the Platinum Group Metals, University of York, England, July 21-26, 1996, p. 48 (1996)

Toroid NMR Studies, J. W. Rathke, R. J. Klingler, M. J. Chen, K. W. Kramarz, and R. E. Gerald, Proc. of the Tenth DOE/BES Heterogeneous Catalysis and Surface Chemistry Research Conf., Lake Conroe, TX, May 21-24, 1996, pp. 121-124 (1996)

In Situ Diffusion Measurements in an Electrochemical Cell, R.E. Gerald, R. J. Klingler, J. W. Rathke, and K. Woelk, Program Binder for the 37th Experimental Nuclear Magnetic Resonance Conf., Pacific Grove, CA, March 17-22, 1996, p. 190 (1996)

Imaging of Diffusion Using Asymmetric z-Magnetization Grids in Toroid Cavity Probes, K. Woelk, R. E. Gerald, R. J. Klingler, and J. W. Rathke, Program Binder for the 37th Experimental Nuclear Magnetic Resonance Conf., Pacific Grove, CA, March 17-22, 1996, p. 78 (1996)

Metallophthalocyanines for Hydrocarbon Activation: Rhodium Phthalocyanine Radicals, M. J. Chen and J. W. Rathke, Presented at the Catalysis Club of Chicago, Spring Symp., Argonne, IL, May 14, 1996

In Situ NMR Investigations of Hydroformylation in Supercritical Carbon Dioxide and Polarity Effects of Organic Solvents on Precatalytic Species, K. W. Kramarz, R. J. Klingler, and J. W. Rathke, Presented at the Catalysis Club of Chicago, Spring Symp., Argonne, IL, May 14, 1996

NMR for Solids, J. W. Rathke, CHEMTECH 25(10), 48 (1995)

Applications of Toroids in High-Pressure NMR Spectroscopy, R. J. Klingler, J. W. Rathke, K. Woelk, K. W. Kramarz, and R. E. Gerald, Am. Chem. Soc., Division of Fuel Chemistry Preprints 40(3), 415-419 (1995)

Composite 90° and 180° Pulses to Compensate for Radiofrequency Gradients in Toroid NMR Detectors, K. Woelk and J. W. Rathke, J. Magn. Reson. A 115(1), 106-115 (1995)

Radial Distributions of ⁷Li⁺ Ions in Polyethylene Oxide in a Cylindrical Cavity Imager, R.E. Gerald, J. W. Rathke, and R. J. Klingler, Abstracts, 37th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 23-27, 1995, p. 151 (1995)

Persistent Rh(II) Phthalocyanine Radicals, M. J. Chen and J. W. Rathke, Presented at the Int. Chemical Congress of Pacific Basin Societies, Honolulu, HI, December 17-22, 1995

Applications of Toroids in High-Pressure NMR Spectroscopy, R. J. Klingler, J. W. Rathke, K. Woelk, K. W. Kramarz, and R. E. Gerald, Presented at the Am. Chem. Soc. National Meeting, Chicago, IL, August 20-24, 1995

Radial Distribution of ⁷Li⁺ Ions in Polyethylene Oxide in a Cylindrical Cavity Imager, R.E. Gerald, J. W. Rathke, and R. J. Klingler, Presented at the 37th Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 23-28, 1995

Metallophthalocyanine Radicals in Catalysis, M. J. Chen and J. W. Rathke, Presented at the Catalysis Club of Chicago, Spring Symp., Argonne, IL, May 9, 1995

High-Pressure NMR Studies in Supercritical Media, R. J. Klingler, J. W. Rathke, and K. W. Kramarz, Presented at the Catalysis Club of Chicago Spring Symp., Argonne, IL, May 9, 1995

Supercritical Hydroformylations, J. W. Rathke and R. J. Klingler, Presented at the 209th Am. Chem. Soc. National Meeting, Division of Industrial and Engineering Chemistry, Anaheim, CA, April 2-6, 1995

High Pressure NMR Studies of Homogeneous Catalytic Processes, J. W. Rathke, R. J. Klingler, M. J. Chen, and K. Woelk, Trends in Organometallic Chemistry 1, 117-130 (1994)

The Toroid Cavity NMR Detector, K. Woelk, J. W. Rathke, and R. J. Klingler, J. Magn. Reson. A 109, 137-146 (1994)

Reversible Hydrocarbon Activation by Rhodium Phthalocyanine Dimer [(R₈Pc)Rh]₂ (R₈Pc^2- = Dianion of 1,4,8,11,15,18,22,25-Octa-n-Pentylphthalocyanine), M. J. Chen and J. W. Rathke, Organomet. 13(12), 4875-4880 (1994)

High-Pressure NMR Investigation of Hydrogen Atom Transfer and Related Dynamic Processes in Oxo Catalysis, R. J. Klingler and J. W. Rathke, J. Am. Chem. Soc. 116, 4772-4785 (1994)

Recent High-Pressure NMR Spectral and Imaging Studies, J. W. Rathke, R. J. Klingler, M. J. Chen, and K. Woelk, Proc. of the Ninth DOE/BES Heterogeneous Catalysis and Surface Chemistry Research Conf., Oconomowoc, WI, May 24-27, 1994, pp. 124-127 (1994)

NMR Spectral and Imaging Studies at High Pressure, R. J. Klingler and J. W. Rathke, Presented at the University of Wisconsin, Madison, WI, November 21-22, 1994

NMR and Supercritical Hydroformylations, J. W. Rathke, R. J. Klingler, and K. Woelk, Presented at the Shell Development Company, Houston, TX, October 10, 1994

Rotating Frame NMR Microscopy, K. Woelk, J. W. Rathke, and R. J. Klingler, Presented at the Rocky Mountain Conf. on Analytical Chemistry, Denver, CO, July 31–August 5, 1994

High Pressure NMR Spectral and Imaging Studies, R. J. Klingler, K. Woelk, and J. W. Rathke, Presented at the University of Illinois at Chicago, IL, July 14, 1994

Rotating-Frame NMR Microscopy Using Toroid Cavity Detectors, K. Woelk, J. W. Rathke, and R. J. Klingler, J. Magn. Reson. A 105, 113-116 (1993)

Low Symmetry in the Crystal Structure of (Octapentylphthalocyaninato) (methyl)rhodium(III), M. J. Chen, J. W. Rathke, and J. C. Huffman, Organomet. 12(11), 4673-4677 (1993)

Dynamics of Room-Temperature Melts: Nuclear Magnetic Resonance Measurements of Dialkylimidazolium Haloaluminates, S. Takahashi, M.-L. Saboungi, R. J. Klingler, M. J. Chen, and J. W. Rathke, J. Chem. Soc. Faraday Trans. 89(19), 3591-3595 (1993)

Cobalt Carbonyl Catalyzed Olefin Hydroformylation in Supercritical Carbon Dioxide, J. W. Rathke and R. J. Klingler, Patent No. 5,198,589, issued March 30, 1993

Rotating Frame NMR Microscopy, K. Woelk, J. W. Rathke, and R. J. Klingler, Presented at the Int. Conf. on Magnetic Resonance Microscopy, Heidelberg, Germany, September 6-9, 1993

Rotating Frame NMR Microscopy, K. Woelk, J. W. Rathke, and R. J. Klingler, Presented at the University of Bonn, Germany, June 28–July 9, 1993

High Pressure NMR Investigations Using Toroid Detectors, K. Woelk, J. W. Rathke, and R. J. Klingler, Presented at the University of Bonn, Germany, June 28–July 9, 1993

High-Pressure NMR Studies of the OXO Catalyst in Supercritical Media, R. J. Klingler and J. W. Rathke, Presented at the Gordon Research Conf. on Organometallic Chemistry, Newport, RI, July 12-16, 1993

Unusual Tautomerism Involving Proton Migration between Metal and Pyrrolic Nitrogen in a Hydridorhodium Phthalocyanine Complex, M. J. Chen and J. W. Rathke, J. Chem. Soc. 4, 308-309 (1992)

Hydrogen Activation by Soluble Metal Oxide Complexes, R. J. Klingler, T. R. Krause, and J. W. Rathke, Homogeneous Transition Metal Catalyzed Reactions, Advances in Chemistry Series No. 230, Eds., W. R. Moser and D. W. Slocum, Am. Chem. Soc., Washington, DC, pp. 337-348 (1992)

Thermodynamics for the Hydrogenation of Dicobalt Octacarbonyl in Supercritical Carbon Dioxide, J. W. Rathke, R. J. Klingler, and T. R. Krause, Organomet. 11(2), 585-588 (1992)

Thermodynamics for the Hydrogenation of Dimanganese Decacarbonyl, R. J. Klingler and J. W. Rathke, Inorg. Chem. 31(5), 804-808 (1992)

NMR Measurements in Solutions of Dialkylimidazolium Haloaluminates, S. Takahashi, M.-L. Saboungi, R. J. Klingler, M. J. Chen, and J. W. Rathke, Proc. of the Eighth Int. Symp. on Molten Salts, 181st Electrochem. Soc. Meeting, St. Louis, MO, May 17-22, 1992, Vol. 92-16, p. 343 (1992)

T₁-Relaxation Measurements Using Toroid R. F. Coils in High Pressure NMR Investigations, K. Woelk, J. W. Rathke, and R. J. Klingler, Presented at the IBM Research Center in California, San Jose, CA, August 27, 1992

Activation of Hydrocarbons by Soluble Rhodium Phthalocyanine Complexes, M. J. Chen and J. W. Rathke, Presented at the 202nd National Meeting of the Am. Chem. Soc., Washington, DC, August 23-28, 1992

High Pressure NMR Investigation of Dynamic Processes which Affect the Oxo Catalyst, R. J. Klingler and J. W. Rathke, Presented at the University of Miami, Coral Gables, FL, March 13, 1992

Homogeneous Catalytic Hydrogenation of Carbon Monoxide, R. J. Klingler and J. W. Rathke, Progress in Inorganic Chemistry, Vol. 39, Ed., S. J. Lippard, John Wiley & Sons, New York, pp. 113-180 (1991)

Propylene Hydroformylation in Supercritical Carbon Dioxide, J. W. Rathke, R. J. Klingler, and T. R. Krause, Organomet. 10(5), 1350-1355 (1991)

Process to Solubilize Phthalocyanines and Metallophthalocyanines, J. W. Rathke, M. J. Chen, and C. M. Fendrick, DOE Case No. S-68,413, Statutory Invention Registration filed October 28, 1991

Toroids as NMR Detectors in Metal Pressure Probes and in Flow Systems, J. W. Rathke, Patent No. 5,045,793, issued September 3, 1991

Oxo Chemistry in Supercritical Carbon Dioxide, T. R. Krause, J. W. Rathke, and R. J. Klingler, Presented at the Annual AIChE Meeting on Supercritical Fluids, Los Angeles, CA, November 17-22, 1991

Unusual Tautomerism of a Hydridorhodium Phthalocyanine, M. J. Chen, J. W. Rathke, and R. J. Klingler, Presented at the Gordon Research Conf. on Organometallic Chemistry, Newport, RI, July 15-19, 1991

Hydroformylation Catalysis in Supercritical Media, R. J. Klingler and J. W. Rathke, Presented at the Gordon Research Conf. on Organometallic Chemistry, Newport, RI, July 15-19, 1991

Nucleophilic Hydrogen Activation, R. J. Klingler and J. W. Rathke, Presented at the Third DOE/BES Organometallic Chemistry and Homogeneous Catalysis Research Conf., Madison, WI, June 3-5, 1991

High-Pressure NMR Studies of Catalytic Processes in Supercritial Medium, R. J. Klingler and J. W. Rathke, Presented at the Amoco-Argonne Coal Chemistry Distinguished Seminar Series, Naperville, IL, June 10, 1991

Catalytic Reactions in Supercritical Fluids and Methane Activation, J. W. Rathke, M. J. Chen, and R. J. Klingler, Presented at the Third DOE/BES Organometallic Chemistry and Homogeneous Catalysis Research Conf., Madison, WI, June 3-5, 1991

Peripherally Substituted Phthalocyanines, M. J. Chen, J. W. Rathke, S. Sinclair, and D. W. Slocum, J. Macromol. Sci. Chem. A27(9-11), 1415-1431 (1990)

Autoxidation of Trimethylamine in Aqueous Solutions, M. J. Chen, J. C. Linehan, and J. W. Rathke, J. Organ. Chem. 55, 3233-3236 (1990)

Hydrogen and Methane Activation Studies Using Soluble Rhodium Phthalocyanine Dimers, M. J. Chen and J. W. Rathke, Presented at the 14th Int. Conf. on Organometallic Chemistry, Detroit, MI, August 19-24, 1990

Hydrogen Activation by Soluble Metal Oxide Complexes, R. J. Klingler, T. R. Krause, and J. W. Rathke, Presented at the Am. Chem. Soc. Meeting, Boston, MA, April 22-27, 1990

Catalytic Chemistry in Supercritical Media, J. W. Rathke, R. J. Klingler, and M. J. Chen, Presented at the Basic Energy Sciences Catalysis and Surface Chemistry Research Meeting, Gaithersburg, MD, March 26-28, 1990

Regiospecific Ortho-Lithiation of Phthalocyanines: A Route for One-Step Synthesis of Highly Soluble Trimethylsilyl Substituted Phthalocyanines, M. J. Chen, C. M. Fendrick, R. A. Watson, K. S. Kinter, and J. W. Rathke, J. Chem. Soc., Perkin Trans. 1, 1071-1073 (1989)

Comparative Energy Barriers for Hydrogen Activation by Homogeneous and Heterogeneous Metal Oxide Catalysts, R. J. Klingler, T. R. Krause, and J. W. Rathke, Catal. Lett. 3(5-6), 347-357 (1989)

Toroid Detectors in Pressure Probes, J. W. Rathke, J. Magn. Reson. 85, 150-155 (1989)

Homologation of Methanol Catalyzed by Manganese Carbonyl in Tertiary Amine-Methanol Solutions, M. J. Chen and J. W. Rathke, Organomet. 8(2), 515-520 (1989)

Soluble Transition Metal Derivatized Phthalocyanine Monomers, M. J. Chen, J. W. Rathke, M. Parker, and D. W. Slocum, Proc. of the Macromolecular-Metal Complexes Symp., Lawrenceville, NJ, July 23-28, p. 22 (1989)

Macromolecular Transition Metal Complexes, D. W. Slocum, M. J. Chen, C. M. Fendrick, J. W. Rathke, R. A. Watson, S. Sinclair, and K. S. Kinter, Kurt Mislow Emeritus Symp., Princeton University, p. 1 (1989)

Peripherally Substituted Phthalocyanines, M. J. Chen, J. W. Rathke, S. Sinclair, and D. W. Slocum, Presented at the Macromolecule-Metal Complexes Symp., Lawrenceville, NJ, July 23-28, 1989

Silane-Silanol Dehydrocondensation. The Microscopic Reverse of Hydrogen Activation by an Organometallic Oxide Complex, R. J. Klingler, T. R. Krause, and J. W. Rathke, J. Organomet. Chem. 352(1-2), 81-94 (1988)

Soluble Phthalocyanine Transition Metal Complexes, D. W. Slocum, M. J. Chen, C. M. Fendrick, J. W. Rathke, R. A. Watson, S. Sinclair, and K. S. Kinter, Extended Abstracts, XIIIth Int. Conf. on Organometallic Chemistry, Torino, Italy, September 1988, Paper 0189-1 (1988)

Homologation of Methanol Catalyzed by Manganese Carbonyl in Alkali-Metal Formate-Methanol Solutions, M. J. Chen and J. W. Rathke, Organomet. 6, 1833-1838 (1987)

Catalyst for Producing Lower Alcohols, J. W. Rathke, R. J. Klingler, and J. J. Heiberger, Patent No. 4,656,152, issued April 7, 1987

Soluble Oxide Chemistry at High Pressure, J. W. Rathke and R. J. Klingler, Presented at the Sixth DOE Catalysis and Surface Chemistry Research Conf., Gaithersburg, MD, October 14-16, 1987

Formates in Methanol Synthesis? The Reversible Production of Methyl Formate from Coordinated Formate, R. J. Klingler and J. W. Rathke, Organomet. 5, 2568 (1986)

Exploring Catalytic Methanol Synthesis Using Soluble Metal Oxide Complexes, R. J. Klingler, I. Bloom, and J. W. Rathke, Am. Chem. Soc. Div. Petr. Chem. Prepr. 31, 61 (1986)

Exploring Catalytic Methanol Synthesis Using Soluble Metal Oxide Complexes, R. J. Klingler, I. Bloom, and J. W. Rathke, Presented at the 191st National Meeting of the Am. Chem. Soc., New York, NY, April 13-18, 1986

Thermodynamics for the Addition of Alkyltin Hydrides to Carbon Dioxide, R. J. Klingler, I. Bloom, and J. W. Rathke, Organomet. 4, 1893-1894 (1985)

Selective Homogeneous Catalysts for the Conversion of Methanol to Ethanol, M. J. Chen, H. M. Feder, J. W. Rathke, S. A. Roth, and G. D. Stucky, Ann. N.Y. Acad. Sci. 415, 152-158 (1984)

Methyl Transfer to Nucleophilic Metal Carbonylate Anions in Catalytic Methanol Homologation, S. A. Roth, G. D. Stucky, H. M. Feder, M. J. Chen, and J. W. Rathke, Organomet. 3(5), 708-714 (1984)

New Lead-Based Catalyst Turns Water and Coal into Alcohol, J. W. Rathke and R. J. Klingler, Logos 2(2), 2-7 (1984)

Catalytic Methanol Synthesis from Carbon Monoxide and Water, R. J. Klingler and J. W. Rathke, J. Am. Chem. Soc. 106(24), 7650-7652 (1984)

Catalytic Conversion of CO and H₂O to Alcohols, R. J. Klingler and J. W. Rathke, Am. Chem. Soc. Division of Petroleum Chemistry Preprints 29, 596 (1984)

Ethanol Production Method and System, M. J. Chen and J. W. Rathke, Patent No. 4,476,334, issued October 9, 1984

Homogeneous Catalytic Methanol Homologation, M. J. Chen and J. W. Rathke, Presented at Florida Conf. on Fundamental Steps in Catalysis, Palm Coast, FL, April 15-19, 1984

Catalytic Conversion of CO and H₂O to Alcohols, J. W. Rathke and R. J. Klingler, Presented at the 187th National Meeting of the Am. Chem. Soc., St. Louis, MO, April 8-13, 1984

A New Catalytic Pathway for Methanol Synthesis, J. W. Rathke and R. J. Klingler, Presented at the Fifth DOE Meeting on Heterogeneous Catalysis, Gaithersburg, MD, November 7-9, 1983

Catalytic Homologation of Methanol in Basic Media, M. J. Chen and J. W. Rathke, Presented at the 1983 NSF Organometallic Chemistry Workshop, Tucson, AZ, June 1-4, 1983

Selective Homologation of Methanol Catalyzed by Transition Metal Complexes in Methanol-Amine Solutions, M. J. Chen, H. M. Feder, and J. W. Rathke, Presented at the Int. Symp. on Catalytic Reactions of One Carbon Molecules, Bruges, Belgium, June 1982

Selective Homologation of Methanol Catalyzed by Transition Metal Complexes in Methanol-Amine Solutions, M. J. Chen, H. M. Feder, and J. W. Rathke, J. Mol. Catal. 17, 331-337 (1982)

A General Homogeneous Catalytic Method for the Homologation of Methanol to Ethanol, M. J. Chen, H. M. Feder, and J. W. Rathke, J. Am. Chem. Soc. 104, 7346-7347 (1982)

Mechanism of the Homogeneous Hydrogenation of Carbon Monoxide, J. W. Rathke and H. M. Feder, Proc. of the Eighth Conf. on Catalysis of Organic Reactions, New Orleans, LA, June 2-4, 1980, pp. 219-234 (1981)

Experimental and Theoretical Studies of Mechanisms in the Homogeneous Catalytic Activation of Carbon Monoxide, H. M. Feder, J. W. Rathke, M. J. Chen, and L. A. Curtiss, Proc. of the 180th Am. Chem. Soc. Meeting, Catalytic Activation of Carbon Monoxide, Symp. Ser. No. 152, Las Vegas, NV, August 24-29, 1980, pp. 19-34 (1981)

Hydrogenation of Carbon Monoxide and Related Molecules, H. M. Feder and J. W. Rathke, Ann. N. Y. Acad. Sci. 333, 45-57 (February 1980)

Mechanism of the Homogeneous Hydrogenation of Carbon Monoxide to Methanol, J. W. Rathke and H. M. Feder, Presented at Eighth Conf. of the Organic Reaction Catalysis Society, New Orleans, LA, June 2-4, 1980

Hydrogenation of Coal Liquid Utilizing a Metal Carbonyl Catalyst, H. M. Feder and J. W. Rathke, Patent No. 4,152,248, issued May 1, 1979

Catalysis of Carbon Monoxide Hydrogenation by Soluble Mononuclear Complexes, J. W. Rathke and H. M. Feder, J. Am. Chem. Soc. 100, 3623 (1978)

Cobalt-Catalyzed Homogeneous Hydrogenation of Arenes, H. M. Feder and J. W. Rathke, Presented at the Catalysis Club of Chicago, IL, November 14, 1977